Sunday, March 3, 2013

Ruthenium in Organic Synthesis

Ruthenium in
Ruthenium in Organic Synthesis
Shun-Ichi Murahashi (Editor)

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Organometallic Compounds

In this comprehensive book, one of the leading experts, Shun-Ichi Murahashi, presents all the important facets of modern synthetic chemistry using Ruthenium, ranging from hydrogenation to metathesis. In 14 contributions, written by an international authorship, readers will find all the information they need about this fascinating and extraordinary chemistry. The result is a high quality information source and a indispensable reading for everyone working in organometallic chemistry.

From the contents:

Introduction (S.-I. Murahashi)
Hydrogenation and Transfer Hydrogenation (M. Kitamura and R. Noyori)
Oxidations (S.-I. Murahashi and N. Komiya)
Carbon-Carbon Bond Formations via Ruthenacycle Intermediates (K. Itoh)
Carbon-Carbon Bond Formation via pi-Allylruthenium Intermediates (T. Mitsudo)
Olefin Metathesis (R. H. Grubbs)
Cyclopropanation (H. Nishiyama)
Nucleophilic Addition to Alkynes and Reactions via Vinylidene Intermediates (P. Dixneuf)
Reactions via C-H Activation (N. Chatani)
Lewis Acid Reactions (E. P. Kundig)
Reactions with CO and CO2 (T. Mitsudo)
Isomerization of Organic Substrates Catalyzed by Ruthenium Complexes (H. Suzuki)
Radical Reactions (H. Nagashima)
Bond Cleavage Reactions (S. Komiya)

  • Rank: #4654481 in Books
  • Published on: 2004-10-15
  • Original language: English
  • Number of items: 1
  • Dimensions: 9.69" h x .91" w x 7.32" l, 1.93 pounds
  • Binding: Hardcover
  • 398 pages

Description #1 by LoadLib:

Review From the Review s:oAUCoAOH Activation is a collection of 12 independent chapters, written by renowned authors. oAae The descriptions of future perspectives, applications oAae experimental procedures at the end of the chapters will be very valuable to readers, particularly students. oAae I strongly recommend the book oAae intellectually rewarding, and promising avenues of research within organic and organometallic chemistry. It is an essential reference source for the practitioners in the field for many years to come, and it should have a privileged spot on many bookshelves.oAY (Rub+en Mart+in Romo, Angewandte Chemie, Vol. 50, 2011)From the Back Cover Table of Contents- Synthesis in the Key of Catellani: Norbornene-Mediated ortho CoAOH Functionalization- Mechanistic Considerations in the Development and Use of Azine, Diazine and Azole N-Oxides in Palladium-Catalyzed Direct Arylation- Palladium and Copper Catalysis in Regioselective, Intermolecular Coupling of CoAOH and CoAOHal Bonds- Pd-Catalyzed CoAOH Bond Functionalization on the Indole and Pyrrole Nucleus- Remote CoAOH Activation via Through-Space Palladium and Rhodium Migrations- Palladium-Catalyzed AryloAOAryl Bond Formation Through Double CoAOH Activation- Palladium-Catalyzed Allylic CoAOH Bond Functionalization of Olefins- Ruthenium-Catalyzed Direct Arylations Through CoAOH Bond Cleavages- Rhodium-Catalyzed CoAOH Bond Arylationof Arenes- Cross-Dehydrogenative Coupling Reactions of sp3-Hybridized CoAOH Bonds- Functionalization of CarbonoAOHydrogen Bonds Through Transition Metal Carbenoid Insertion- Metal-Catalyzed Oxidations of CoAOH to CoAON Bonds

Description #2 by Alibris:


Description #3 by shopoin.info:

"Molecular ruthenium catalysts, during the last decade, have provided new indispensable synthetic methods that cannot be promoted by other catalysts, and they now constitute an emerging field for the selective preparation of fine chemicals. The major reaction types for carbon-carbon and carbon-heteroatom bond formation, most of them with atom economy, are comprehensively discussed by leading experts. The authors highlight the most important discoveries in ruthenium catalysis and propose activation processes, some of them being still controversial. They illustrate the innovation and usefulness in organic synthesis of specific reactions including carbocyclization, cyclopropanation, olefin metathesis, carbonylation, oxidation, transformation of silicon containing substrates, and show novel reactions operating via vinylidene intermediates, radical processes, inert bonds activation as well as catalysis in water. Therefore, the reader will receive a balanced view of this rapidly developing field.File Size: 7503 KBPrint Length: 331 pages Publisher: Springer; 1 edition (March 18, 2005) Sold by: Amazon Digital Services, Inc.Language: EnglishASIN: B000UHNEP6"